If we buy their light novels there will be a good chance for us (fans) to get a new season after they make SNS (shakugan no shana) or HNG (Hayate no gotoku).

Zero No Tsukaima Season 1 2006

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Louise is in a school for magic. She uses magic to get her a familiar which is usually an animal or a thing. She gets Saito, a human. Coming there he gets a set of runes on the back of his hand that will let him use any practical weapon (i.e. normal swords and guns, not play/practice weapons). This mostly setup with Louise and Saito with a school setting.

2006-07-03, Episode 1 Louise the Zero
2006-07-10, Episode 2 The Peasant Familiar
2006-07-17, Episode 3 The Subtle Heat's Allure
2006-07-24, Episode 4 The Maid's Crisis
2006-07-31, Episode 5 The Princess de Tristain
2006-08-07, Episode 6 The Thief's True Identity
2006-08-14, Episode 7 Louise's Part-Time Job
2006-08-21, Episode 8 Tabitha's Secret
2006-08-28, Episode 9 Louise's Change of Heart
2006-09-04, Episode 10 The Princess' Request
2006-09-11, Episode 11 Louise's Marriage
2006-09-18, Episode 12 The Zero Secret Treasure
2006-09-25, Episode 13 Louise the Void

Zero No Tsukaima: Futatsuki no Kishi 2007
ゼロの使い魔 ~双月の騎士~

Season 2

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This sequel is a continuation of the previous season, not long after the war. Louise and Saito seemingly getting along now since she knows that he had given up his only chance to return to Tokyo for her. The story continues as Louise begins to use Void Magic from a mysterious secret book she had received from her majesty Henrietta, while a new villain has appeared in town causing trouble.

2007-07-09, Ep1 Her Majesty, the Queen's Zero
2007-07-16, Ep2 The Vow of Wind and Water
2007-07-23, Ep3 The Paladin's Sword
2007-07-30, Ep4 The Three Vallière Sisters
2007-08-06, Ep5 The Spy's Seal
2007-08-13, Ep6 The Queen's Vacation
2007-08-20, Ep7 The Underground Secret Document
2007-08-27, Ep8 The Magic Institute's Crisis
2007-09-03, Ep9 The Atonement of Flames
2007-09-10, Ep10 The Enemy on Snowy Alps
2007-09-17, Ep11 The Silver Pentecost
2007-09-24, Ep12 The Farewell Wedding Ceremony

Zero No Tsukaima: Princess no Rondo 2008
ゼロの使い魔~三美姫の輪舞 (プリンセッセのロンド)~

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Following Saito's heroic actions in the War with Albion in season two, Saito & Louise return to Tristain, only to have the runes which bind Saito & Louise disappear. Saito & Louise struggle with a relationship no longer defined as Master & Familiar, as they search for an Elf who has the power to restore the dead to life, and may hold the key to understanding Saito's loss of the Gandalfr's power.

2008-07-06 3.1-The Seal of the Familiar
Tsukaima no kokuin

2008-07-13 3.2-Forest Fairy
Mori no yousei

2008-07-20 3.3-Return of the Hero
Eiyuu no okaeri

2008-07-27 3.4-The Rumored Accepted Student
Uwasa no hennyuu sei

2008-08-03 3.5-The Alluring Women's Bath
Miwaku no Joshiburo

2008-08-10 3.6-The Taboo Magical Potion
Kindan no mahou yaku

2008-12-25 3.6.5-Seductive_Beach-OVA
Miwaku no Sunahama
Also Yūwaku no Sunahama

2008-08-17 3.7-Slepnir Dance Party

2008-08-24 3.8-The Eastern Pursuit!
osutoranto gou no tsuiseki

2008-08-31 3.9-Tabitha's Sister
TABASA no Imouto

2008-09-07 3.10-Border_Mountain_Pass
kokkyou no touge
Kokyou no touge

2008-09-14 3.11-Captive_in_Alhambra
aahanbura no toriko

2008-09-21 3.12-Wings of Freedom
jiyuu no tsubasa

Zero no Tsukaima F (ゼロの使い魔F) 2012

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Zero no F
Zero no Tsukaima F is the fourth and final season. Episode one started on January 7, 2012; and has continued the adventures left off by the previous seasons. Romalia, his Holiness the Pope, and a grave danger have been introduced in this season.

2012-01-07, Ep1 Louise of the Holy Kingdom
2012-01-14, Ep2 The Priestess of Aquileia
2012-01-21, Ep3 The Insanity of the King of Ignorance
2012-01-28, Ep4 The Queen's Reward
2012-02-04, Ep5 De Ornielle's Maidens
2012-02-11, Ep6 A Chaotic Hot Spring
2012-02-18, Ep7 The Desert Elf
2012-02-25, Ep8 Escape Though the Sewer
2012-03-03, Ep9 Tabitha's Coronation
2012-03-10, Ep10 Awakening of a Natural Disaster
2012-03-17, Ep11 Louise's Choice
2012-03-24, Ep12 The Familiar Of Zero Final Episode